If you have been invited to a "white tie event" the most formal of all events, then a white skinny tie might be just what to wear. Be sure to double check, however, that white skinny neckties are allowed as sometimes such event require specific ties like bow ties. White skinny ties are rarely used on other occasions but if you really want stand out, try a white skinny tie with an all black outfit.
Nothing makes an outfit stand out more than contrast. And if you prefer to blend or invisibility is your thing, try a Jacob Alexander knit skinny tie in white with a white shirt.